use the example posted here:http://unity3d.com/support/documentation/ScriptReference/WWW.html
// Get the latest webcam shot from outside "Friday's" in Times Square
var url = "http://images.earthcam.com/ec_metros/ourcams/fridays.jpg";
function Start () {
// Start a download of the given URL
var www : WWW = new WWW (url);
// Wait for download to complete
yield www;
// assign texture
renderer.material.mainTexture = www.texture;
}
"You should not write loops that spin until download is done".